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V.35,no.4,Dec 2023 |
https://doi.org/10.5764/TCF. |
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Journal |
Textile Coloration and Finishing |
Year / Vol., Issue, Month |
2021 / V.33,no.1,Mar |
Title |
Detoxification Properties of Guanidinylated Polyethyleneimine
Treated Polypropylene Non-woven Fabric Against Chemical
Warfare Agents |
Authors |
Jiyun Kim, Woong Kwon, Changkyu Kim and Euigyung Jeong |
Institution/Affiliations |
Kyungpook National University |
Pages/Total page |
pp.1 ~ 9 / 9 |
Language |
Korean |
Abstract |
This study aims to prepare the fabric with detoxification properties against
chemical warfare agent by the simple treatment. For this purpose, polypropylene
non-woven fabric(PP) was treated with polyethyleneimine(PEI) and guanidinylated PEI
and detoxification properties of the guanidinylated PEI treated PP were evaluated using
diisopropylfluorophosphate(DFP), as a chemical warfare agent simulant, and compared
with the untreated and PEI treated PP. The half-lives of DFP on guanidinylated PEI
treated PP and untreated PP were 334 min and 714 min, respectively. The half-life of
DFP with guanidinylated PEI treated PP was 53.22% shorter than with untreated PP.
This result shows that guanidine group in guanidinylated PEI treated PP was acted as
a base catalyst for hydrolysis of DFP and decreased half-life of DFP. Therefore, it is
expected that guanidinylated PEI treatment can be an simple pathway to prepare the
detoxification fabric material for protective clothing against chemical warfare agents. |
Keywords |
guanidine, guanidinylated polyethyleneimine, chemical warfare agent, organic
phosphorus nerve agents, diisopropylfluorophosphate |
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Reference |
http://koreascience.or.kr/journal/OSGGBT.page?&lang=ko |
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