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⵵/ȣ 1997 / ȣ: V.9,no.6,Dec
1() ũĸȭ (IV) -º ɼ
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/ 79 ~ 86 : 8
() Korean
ʷ The microcapsule for thermochromism is based on the polymerization reaction between epoxy resin and amine curing agent. The preparation process of microcapsule is based on dissolving or dispersing a hydrophobic core materials[one-dye-black(OBD), bis-phenol A(BPA), cetyl alcohol] in an aqueous solution of gelatin, epoxy resin and isophorondiamine(IPDA) ; the gelatin and IPDA used as a dispersion stabilizer and an hardening agent, respectively. The structures of epoxy resin and microcapsule materials have been analyzed by FT-IR and UV/Vis spectra. The mean diameter and size distribution of microcapsule are 1.46~1.75 and 1.42, respectively. The DSC thermograms of microcapsules indicated 2 kinds of endothermic peaks at 47 and 322. This is possibly corresponding to the melting peak of core material and wall meterial. These microcapsules are applied to the fabric by printing. Complex finished fabric showed a good wear resistance on rubbing test and the print pattern to the cotton fabric showed a reversible thermochromism ; are 580 nm below 4 and 276.5nm above 4 in ethanol/water(2/8), respectively.
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