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⵵/ȣ 1990 / ȣ: V.2,no.4,Dec
1() Thermotropic copoly(ester amide) ռ ؼ
2(Ÿ) Syntheses of Thermotropic Liquid-Crystalline Copoly(ester amide)s Containing a Flexible Spacer in the Main Chain and Their Structure Interpretation
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ʷ Syntheses and liquid-Crystallinites of thermotropic copoly (ester amide)s were investigated. The three components melt polycondensation of 4,4\\\'-dicarboxy-, -diphenoxyalkane as an A component, 4-4\\\'diacetoxybiphenyl as a B, and p-N-acetoxy-aminobenzoic acid as a C gave the thrmotropic copoly(ester amide)s containing a flexible splacer in the polymer backbone. Diacetylated hydroquinone, methyl hydroquinone, chlorohydroquinone, and phenyl hydroquinone were used as anther B components. A polymer(6BPAB) having 10 mol% of C component and hexamethylene space. showed a typical nematic texture between . The melting points of the members of this series of polymers increased with decreasing methylene spacer. The polymer structure and mesomorphic nature were examined by solid and solution spectroscopy, cross polarizing microscopy with a hot stage, and X-ray diffactometry.
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