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 년도별 목차보기 |
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| 발행년도/권호 |
1994 년 / 권호: V.6,no.2,Jun |
| 논문제목1(원어) |
중성염이 Poly(ethylene terephthalate) 직물의 알칼리 가수분해에 미치는 영향(II) |
| 논문제목2(타언어) |
Effects of Neutral Salts on Alkaline Hydrolysis of Poly(ethylene terephthalate) (II) - Anionic Effect - |
| 저자(원어) |
도성국 (동아대학교 천연섬유학과) 조환 (영남대학교 섬유공학과 |
| 저자(타언어) |
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| 소속(원어) |
도성국 (동아대학교 천연섬유학과) 조환 (영남대학교 섬유공학과 |
| 소속(타언어) |
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| 시작/끝
페이지 |
10 ~ 16 총페이지 : 7 |
| 언어(원어) |
Korean |
| 초록 |
Neutral salts have negative or positive effects on the rates of many chemical reactions and also on the rates of acidic and alkaline hydrolysis of carboxylic esters. The direction of neutral salt effects on the hydrolysis of ester depends on the charge of esters. Neutral salts accelerate alkaline hydrolysis of esters with negative charge, but decelerate alkaline hydrolysis of esters with positive charge, and have little effect on the alkaline hydrolysis of neutral esters. It is expected that the rate of the alkaline hydrolysis of Poly(ethylene terephthalte) (PET), polymeric solid carboxylic polyester with carboxyl end group at the polymer end, is also influenced positively by neutral salts. In the present work, to clarify the mechanism of the neutral salt effect on the alkaline hydrolysis of PET, many salts with different anions like NaF, NACl, NaBr, NaI were added to the aqueous alkaline solutions. Then PET was hydrolyzed with aqueous solutions of many salts in alkali metal hydroxides under various conditions. Some conclusions obtained from the experimental results were summarized as follows. The reaction rate of the alkaline hydrolysis of PET was increased by the addition of neutral salts and In k was increased nearly linearly with the square root of ionic strength of reaction medium. This fact suggested that the ionic strength effect by Debye-Huckel and Bronsted theory was exerted on the reaction. The specific salt effect was also observed. The reaction rate was increased with the decrease in the nucleophilicity of anions of neutral salts, i.e., in the order of <<<. It was thought that the reaction rate was increased in the order of <<<. because the completion of anions with for carbonyl carbon became weaker with the decrease in the nucleophilicity and with the increase in the size of anions. |
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