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1995 / ȣ: V.7,no.4,Dec |
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(-ƹ̵-ƹ̵) ü ȭ Ż ȭ |
2(Ÿ) |
A Study on Chemical Cyclodehydration of Aromatic Poly(ether-amide-amic acid)s |
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Ahn, Young Moo (Dept. of Clothing and Textiles, Hansung Univ., Seoul, Korea) |
(Ÿ) |
Ahn, Young Moo (Dept. of Clothing and Textiles, Hansung Univ., Seoul, Korea) |
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Ahn, Young Moo (Dept. of Clothing and Textiles, Hansung Univ., Seoul, Korea) |
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Ahn, Young Moo (Dept. of Clothing and Textiles, Hansung Univ., Seoul, Korea) |
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39 ~ 44 : 6 |
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Korean |
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A study has been made about some correlations in the chemical cyclization of precursors, poly(ether-amide-amic acid)s by treating in solution a mixture of acetic anhydride and pyridine in the presence of 4,4-dimethyl formamide, with the poly(ether-amic acid)s being respectively reacted between trimellitic anhydride chloride and 3 kinds of diamines, i.e., 4,4\\\'-bis(m-aminophenoxy) benzophenone, 2,2\\\'-bis[4-(m-aminophenoxy) phenyl] propane and 4,4\\\'-bis(m-aminophenoxy) diphenyl sulfone. The cyclization of imide ring in the poly(ether-amide-amic acid)s may be regarded as an intramolecular acylation of amide group by o-carboxyl group. As a result of this reseach, the effects on the conversion to poly(ether-amide-imide)s have been found by changing the ratio of cosolvents in the cyclization mixture. |
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