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⵵/ȣ 1995 / ȣ: V.7,no.4,Dec
1() (׸-ƹ̵-ƹ̵) ü ȭ Ż ȭ
2(Ÿ) A Study on Chemical Cyclodehydration of Aromatic Poly(ether-amide-amic acid)s
() Ahn, Young Moo (Dept. of Clothing and Textiles, Hansung Univ., Seoul, Korea)
(Ÿ) Ahn, Young Moo (Dept. of Clothing and Textiles, Hansung Univ., Seoul, Korea)
Ҽ() Ahn, Young Moo (Dept. of Clothing and Textiles, Hansung Univ., Seoul, Korea)
Ҽ(Ÿ) Ahn, Young Moo (Dept. of Clothing and Textiles, Hansung Univ., Seoul, Korea)
/ 39 ~ 44 : 6
() Korean
ʷ A study has been made about some correlations in the chemical cyclization of precursors, poly(ether-amide-amic acid)s by treating in solution a mixture of acetic anhydride and pyridine in the presence of 4,4-dimethyl formamide, with the poly(ether-amic acid)s being respectively reacted between trimellitic anhydride chloride and 3 kinds of diamines, i.e., 4,4\\\'-bis(m-aminophenoxy) benzophenone, 2,2\\\'-bis[4-(m-aminophenoxy) phenyl] propane and 4,4\\\'-bis(m-aminophenoxy) diphenyl sulfone. The cyclization of imide ring in the poly(ether-amide-amic acid)s may be regarded as an intramolecular acylation of amide group by o-carboxyl group. As a result of this reseach, the effects on the conversion to poly(ether-amide-imide)s have been found by changing the ratio of cosolvents in the cyclization mixture.
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