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⵵/ȣ 1996 / ȣ: V.8,no.2,Apr
1() Sodium glycerolate/Glycerol ׿ PET ռ Ư
2(Ÿ) Characteristics of PET Microfiber Fabrics Decomposed by Sodium glycerolate/Glycerol Solution
() Yoon, Jong Ho (Dept. of Industrial Chem., Kyungpook Sanup Univ., Kyungsan, Korea) Huh, Man Woo (Dept. of Textile Eng., Kyungpook Sanup Univ., Kyungsan, Korea) Bae, Jeong Sook (Dept. of Clothing and Textiles, Taegu Univ., Kyungsan, Korea) Cho, Yong Suk (De
(Ÿ) Yoon, Jong Ho (Dept. of Industrial Chem., Kyungpook Sanup Univ., Kyungsan, Korea) Huh, Man Woo (Dept. of Textile Eng., Kyungpook Sanup Univ., Kyungsan, Korea) Bae, Jeong Sook (Dept. of Clothing and Textiles, Taegu Univ., Kyungsan, Korea) Cho, Yong Suk (De
Ҽ() Yoon, Jong Ho (Dept. of Industrial Chem., Kyungpook Sanup Univ., Kyungsan, Korea) Huh, Man Woo (Dept
Ҽ(Ÿ) Yoon, Jong Ho (Dept. of Industrial Chem., Kyungpook Sanup Univ., Kyungsan, Korea) Huh, Man Woo (Dept
/ 16 ~ 24 : 9
() Korean
ʷ Polyester microfiber fabrics were alcoholysed at 120, 140, and 16 in 0.5, 1.0, and 1.5% of sodiumglycerolate/glycerol solutions(NaGR) up to 80% and the characteristic decomposition features were compared and discussed with the results of the hydrolysis done by 5% sodium hydroxide solution(NaOH) at 80, 90, and 10. The resulting activation thermodynamic parameters calculated by the combined use of the Arrhenius equation and the Eyring equation were in NaOH case =- 13.89 kcal/mol, /=-38.12 cal/mol K, and =25.25 kcal/mol and in NaGR case =29.81 kcal/mol, =-2.29 cal/mol K and =30.49 kcal/mol. Since in all cases NaGR-PET system has higher activation thermodynamic parameters, it was concluded that NaGR-PET reaction system is more favorable at high temperatures and occurs in a less selective fashion, in comparison to the NaOH-PET reaction system.
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