|
|
|
|
|
 |
 년도별 목차보기 |
| * 원문 PDF 파일은 로그인 하시기 바랍니다. |
 |
|
| 발행년도/권호 |
2001 년 / 권호: V.13,no.6,Dec |
| 논문제목1(원어) |
아크릴 중합체 및 아크릴-이타코닉산 공중합체/ 디메틸술폭시드 용액의 유변학적 특성의 시간의존성 |
| 논문제목2(타언어) |
Time Dependence of the Rheological Properties of the Solutions of Polyacrylontrile and Acrylonitrile-Itaconic Acid Copolymer in Dimethyl sulfoxide |
| 저자(원어) |
이남순 (동양공업 전문대학 응용화학과) |
| 저자(타언어) |
|
| 소속(원어) |
이남순 (동양공업 전문대학 응용화학과) |
| 소속(타언어) |
|
| 시작/끝
페이지 |
435 ~ 440 총페이지 : 6 |
| 언어(원어) |
Korean |
| 초록 |
This study investigates the rheological properties of in-situ polymerized solutions of polyacrylonitrile(PAN) and acrylonitrile(AN) -itaconic acid(IA) in dimethyl sulfoxide(DMSO) in terms of temperature, concentration, and time. The complex viscosity and storage modulus of the solutions were generally increased with elapsing time, which is ascribable to the three-dimensional pseudostructures formed by strong inter- or Intra-molecular attractions through Polar -CN and -COOH groups. The three-dimensional pseudonetworks would lead to relation of the acrylic solutions in long term. This was more noticeable at higher temperature within the temperature range examined. In the case of 20% solutions one can not observe lower Newtonian flow region in the viscosity curve. Disappearance of lower Newtonian flow region is indicative of heterogeneity of the solution system. Casson Plot of the viscosity data revealed that 20% solutions of PAN and AN-IA copolymer in DMSO clearly demonstrated positive yield stress, ascertaining formation of pseudostructures in the solution syste |
| 키워드 |
|
| 학회지 |
|
| Reference |
|
|
 |
 |
 |
|
|
|
|
간행물정보
한국염색가공학회지
