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⵵/ȣ 2002 / ȣ: V.14,no.1,Feb
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2(Ÿ) The Interpratation of Dyeing Behavior of the Easily Dyeable Polyester Yarn under Atmospheric Pressure by Thermodynamic Parameters
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ʷ In the prior study, the mechanical properties and the dyeability of the easily dyeable polyester grim(EDY) were investigated. In this study, to interpret the dyeing behavior of EDY with C. I. Disperse Violet 1, the thermodynamic parameters of dyeing, such as the standard affinity, the heat of dyeing(the enthalpy change), the entropy change, the diffusion coefficient, and the activation energy of diffusion, were obtained from adsorption isotherms and dyeing rate at various temperatures and compared to these of regular polyester (REG-PET). The heat of dyeing(the enthalpy change) and the entropy change for EDY showed smaller negative values than those for REG-PET. This means that the dye molecules in the EDY are combined more loosely than in the REG-PET and that is due to the flexibility of polymer chains of EDY. The diffusion coefficients of C. I. Disperse Violet 1 into the EDY were larger than those for REG-PET, and the activation energy of diffusion on EDY was smaller than that on REG-PET.
Ű Easily dyeable polyester yarn(EDY); Themodynamic parameter; Disperse dye; C. I. Disperse Violet 1, Diffusion
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