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* PDF α Ͻñ ٶϴ. |
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/ȣ |
2007 / ȣ: V.19,no.1,Feb |
1() |
öó ũδƮ ǥ鰳 |
2(Ÿ) |
Surface Modification of Polyacrylonitrile by Low-temperature Plasma |
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(Ÿ) |
Eun-Deock Seo |
Ҽ() |
泲б ȭаа |
Ҽ(Ÿ) |
Kyungnam University |
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45 ~ 52 : 8 |
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Korean |
ʷ |
Polyacrylonitrile(PAN) fiber was treated with low-temperature plasmas of argon and oxygen for
surface modification, and its surface chemical structure and morphology were examined by a field emission
scanning electron microscope(FESEM) and a Fourier-transform infrared microspectroscopy(IMS). The argon-plasma
treatment caused the only mechanical effect by sputtering of ion bombardment, whereas the oxygen plasma
brought about a chemical effect on the PAN fiber surface. The experimental evidences strongly suggested that
cyclization of nitrile group and crosslinking were likely to occur in the oxygen-plasma treatment. On the other
hand, with the argon-plasma treatment, numerous tiny pits resulted in ranging from several tens to hundreds
nanometers in radius. The plasma sensitivity of functional groups such as C-H, CN, and O-C=O groups in the
PAN fiber was dependent on their chemical nature of bonding in the oxygen-plasma, in which the ester group
was the most sensitive to the plasma. Vacuum-ultraviolet(VUV) radiation emitted during plasma treatment played
no substantial role to alter the surface morphology. |
Ű |
Plasma surface treatment, IMS, FESEM, PAN fiber, morphology |
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Reference |
http://www.koreascience.or.kr/article/ArticleFullRecord.jsp?cn=OSGGBT_2007_v19n1s92_45 |
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