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| 발행년도/권호 |
2016 년 / 권호: V.28,no.2,Jun |
| 논문제목1(원어) |
Anthraquinone을 포함하는 신규 Phthaloperinone 색소의 합성과
특성에 대한 연구 |
| 논문제목2(타언어) |
Synthesis and Properties of New Phthaloperinone Dyes containing
Anthraquinone Moiety |
| 저자(원어) |
전근, 권선영1, 김유진1, 김성훈1 |
| 저자(타언어) |
Kun Jun, Seon Yeong Gwon1, Yu Jin Kim1 and Sung Hoon Kim1* |
| 소속(원어) |
한국화학연구원 그린화학공정연구본부, 1경북대학교 섬유시스템공학과 |
| 소속(타언어) |
Korea Research Institute of Chemical Technology, 1Kyungpook National University |
| 시작/끝
페이지 |
57 ~ 62 총페이지 : 6 |
| 언어(원어) |
Korean |
| 초록 |
Abstract We have synthesized five novel phthaloperinone dyes via a condensation reaction
to be applied as yellow colorants for liquid crystal display(LCD) color filters. The
reaction between 1,8-naphthalic anhydride(1a), 4-chloro-1,8-naphthalic anhydride(1b),
4-bromo-1,8-naphthalic anhydride(1c), 3-nitro-1,8-naphthalic anhydride(1d), 4-nitro-
1,8-naphthalic anhydride(1e) and 1,2-diaminoanthraquinone(2) proceeded readily giving
a product in 72-88% yields. The synthesized dyes were characterized by UV-Vis, mass
spectrometry and elemental analysis. The spectral properties and thermal stability of the
dyes were examined. The dyes absorb at around 400-450nm. All five dyes showed satisfactory
thermal stability: the dyes retain 99-100% of its original weight at 300℃, 98-
100% at 350℃, 92-98% at 400℃, and 84-92% at 450℃. We have quantitatively
evaluated the reaction mechanism and reactivity of dye molecules by means of Pariser-
Parr-Pople Molecular Orbital Method(PPP-MO). |
| 키워드 |
Keywords phthaloperinone, dyes, 1,8-naphthalic anhydride, 1,2-diaminoanthraquinone,
TGA analysis, LCD color filter, Pariser-Parr-Pople Molecular Orbital Method(PPP-MO) |
| 학회지 |
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| Reference |
http://www.koreascience.or.kr/article/ArticleFullRecord.jsp?cn=OSGGBT_2016_v28n2_57&ordernum= |
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