| 발행년도/권호 |
2015 년 / 권호: V.27,no.4,Dec |
| 논문제목1(원어) |
신규 Phthaloperinone 색소의 합성과 특성에 대한 연구 |
| 논문제목2(타언어) |
Synthesis and Properties of New Phthaloperinone Dyes |
| 저자(원어) |
전 근·권선영1·김성훈1 |
| 저자(타언어) |
Kun Jun, Seon Yeong Gwon1 and Sung Hoon Kim1 |
| 소속(원어) |
한국화학연구원 그린화학공정연구본부, 1경북대학교 섬유시스템공학과 |
| 소속(타언어) |
Korea Research Institute of Chemical Technology, 1Kyungpook National University |
| 시작/끝
페이지 |
275 ~ 280 총페이지 : 6 |
| 언어(원어) |
Korean |
| 초록 |
Abstract: New series of phthaloperinone dyes were synthesized by the condensation reaction between tetrachloro-phthalic anhydride, 2,3-naphthalene dicarboxylic anhydride and o-phenylenediamine, 1,8-diaminonaphthalene, 1,2-diaminoanthraquinone. These dyes absorb at around 370-490nm. It was found that introduction of naphthalene and anthraquinone moiety on the perinone system produces a large bathochromic shift of 100nm. The synthesized dye 7 containing anthraquinone moiety in perinone chromophoric system exhibited superior heat stability and bright color as yellow chromophore. New dye 7 have been investigated in terms of interacting with volatile organic compound(VOC) EtNH2. The sensing behaviour of the dye 7 toward EtNH2 was studied by UV-vis absorption spectroscopy. Sensing mechanism of dye 7 to EtNH2 was supported by theoretical calculations based on DFT method. |
| 키워드 |
Keywords: phthaloperinone, dyes, EtNH2 sensing, TGA analysis, DMol3 calculation |
| 학회지 |
|
| Reference |
http://www.koreascience.or.kr/article/ArticleFullRecord.jsp?cn=OSGGBT_2015_v27n4_275&ordernum=5 |
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