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⵵/ȣ 2015 / ȣ: V.27,no.2,Jun
1() Silica ϴ Polyurethane dispersion Film
2(Ÿ) Fabrication of Silica-Containing Breathable Waterproof Polyurethane Dispersion Film
() ⡤㸸1Ģ
(Ÿ) Hyun-Ki Shin, Man-Woo Huh1 and Nam-Sik Yoon
Ҽ() ϴб ý۰а, 1ϴб ȣа
Ҽ(Ÿ) Kyungpook National University, Kyungil University
/ 126 ~ 131 : 6
() Korean
ʷ Abstract: Silica-polyurethane hybrid breathable films were prepared and their breathabilities were assessed. Appropriately aggregated silica was prepared through sol-gel reaction of water glass and its particle size ranged 360500nm. The polyurethane dispersion was prepared by the reaction of isophorone diisocyanate(IPDI) as diisocyanate and polytetramethylene glycol(PTMG) and dimethylol propionic acid(DMPA) as polyol, particle size ranging 30120nm. The reaction between isocyanate and hydroxyl group to form urethane bonding was checked by the intensity of the stretch peak of isocyanate at 2270cm-1 in the FT-IR. The silica was incorporated into polyurethane dispersion and casted into film. It was shown that the incorporated silica(15wt.%) increased water vapour permeability of the films by 30100%, and decreased the hydrostatic pressure by 1040%. From the results, it could be concluded that the appropriate hybridization of silica can increase the breathability of polyurethane dispersion film, while minimizing the loss of hydrostatic pressure.
Ű Keywords: breathable, polyurethane, silica, hybrid membrane, water vapor premeability, hydrostatic pressure
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Reference http://www.koreascience.or.kr/article/ArticleFullRecord.jsp?cn=OSGGBT_2015_v27n2_126&ordernum=4

                                                                            
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