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2014 / ȣ: V.26,no.4,Dec |
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Pyrene-Naphthalene Diimide-Pyrene Triad ռ |
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Synthesis and Property of Pyrene-Naphthalene Diimide-Pyrene Triad |
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Hyunji Kim, A-Rong Kim and Jong S. Park |
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ƴб ڰа |
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Dong-A University |
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305 ~ 310 : 6 |
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Korean |
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Abstract: In this study, we presented a newly synthesized pyrene-naphthalene diimide(NDI)-pyrene triad. The optical and structural properties were examined using various characterization techniques. A donor-acceptor-donor triad molecule exhibited a strong charge transfer, though there existed neither intramolecular nor intermolecular hydrogen bonding sites, due to the formation of preferential complementary complex between pyrene and NDI. Powder XRD measurement revealed a sharp and distinctive X-ray patterns, indicating the presence of microcrystalline-like structure. POM images showed anisotropic fingerprint texture similar to that of cholesteric phase, and SEM images showed numerous columnar structures with length of 1 to 10m. Above observation clearly demonstrated that -complementary NDI-pyrene interactions in the traid was strong enough to form columnar aggregates in the long range. |
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Keywords: pyrene-NDI-pyrene triad, UV-visible absorbance, fluorescence, scanning electron microscope(SEM) image, powder XRD, polarized optical microscope(POM) image |
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Reference |
http://www.koreascience.or.kr/article/ArticleFullRecord.jsp?cn=OSGGBT_2014_v26n4_305 |
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