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⵵/ȣ 2014 / ȣ: V.26,no.4,Dec
1() Pyrene-Naphthalene Diimide-Pyrene Triad ռ
2(Ÿ) Synthesis and Property of Pyrene-Naphthalene Diimide-Pyrene Triad
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(Ÿ) Hyunji Kim, A-Rong Kim and Jong S. Park
Ҽ() ƴб ڰа
Ҽ(Ÿ) Dong-A University
/ 305 ~ 310 : 6
() Korean
ʷ Abstract: In this study, we presented a newly synthesized pyrene-naphthalene diimide(NDI)-pyrene triad. The optical and structural properties were examined using various characterization techniques. A donor-acceptor-donor triad molecule exhibited a strong charge transfer, though there existed neither intramolecular nor intermolecular hydrogen bonding sites, due to the formation of preferential complementary complex between pyrene and NDI. Powder XRD measurement revealed a sharp and distinctive X-ray patterns, indicating the presence of microcrystalline-like structure. POM images showed anisotropic fingerprint texture similar to that of cholesteric phase, and SEM images showed numerous columnar structures with length of 1 to 10m. Above observation clearly demonstrated that -complementary NDI-pyrene interactions in the traid was strong enough to form columnar aggregates in the long range.
Ű Keywords: pyrene-NDI-pyrene triad, UV-visible absorbance, fluorescence, scanning electron microscope(SEM) image, powder XRD, polarized optical microscope(POM) image
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Reference http://www.koreascience.or.kr/article/ArticleFullRecord.jsp?cn=OSGGBT_2014_v26n4_305

                                                                            
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