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2013 / ȣ: V.25,no.3,Sept |
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Synthesis of Chemosensor Based on Pyrene and Study for Its Sensing Properties Toward Fluoride Ion |
2(Ÿ) |
Synthesis of Chemosensor Based on Pyrene and Study for Its Sensing Properties Toward Fluoride Ion |
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Hyungjoo Kim, Xiaochuan Li1 and Young-A Son |
(Ÿ) |
Hyungjoo Kim, Xiaochuan Li1 and Young-A Son |
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Chungnam National University, Henan Normal University |
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Chungnam National University, Henan Normal University |
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153 ~ 158 : 6 |
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English |
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In this study, pyrene based chemosensor was synthesized by two step reaction. The chemosensor showed that
high selectivity toward fluoride in DMSO. The fluorescence intensity was drastically increased by binding between
chemosensor and fluoride ion. Absorption and fluorescence spectra were obtained by UV-Vis spectrometer and fluorescence
spectrophotometer. The binding ratio between chemosensor and fluoride ion was also investigated by jobs plot method and
Benesi-Hildebrand plot. The HOMO/LUMO energy levels and electron distribution were calculated and simulated by Material
studio 6.0 Package. |
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pyrene, chemosensor, fluoride, fluorescence, DMSO |
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Reference |
http://www.koreascience.or.kr/article/ArticleFullRecord.jsp?cn=OSGGBT_2013_v25n3_153 |