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 년도별 목차보기 |
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| 발행년도/권호 |
2013 년 / 권호: V.25,no.2,Jun |
| 논문제목1(원어) |
Electrochemical Study for 1,3-Bisdicyanovinylindane
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| 논문제목2(타언어) |
Electrochemical Study for 1,3-Bisdicyanovinylindane
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| 저자(원어) |
Hyungjoo Kim, Boddu Ananda Rao and Young-A Son |
| 저자(타언어) |
Hyungjoo Kim, Boddu Ananda Rao and Young-A Son |
| 소속(원어) |
Chungnam National University |
| 소속(타언어) |
Chungnam National University |
| 시작/끝
페이지 |
89 ~ 93 총페이지 : 5 |
| 언어(원어) |
English |
| 초록 |
Abstract: The electrochemical study has been enjoyed in many areas of chemistry. Through this approach using electrochemical measurement, empirical HOMO and LUMO values can be calculated by three methods such as absorption measurement, cyclicvoltammetry and computational calculations. In this study, 1,3-bisdicyanovinylindane was prepared and investigated toward its optical properties. The absorption intensities were changed depending on changes of pH. These absorption changes are induced by resonance form of 1,3-bisdicyanovinylindane. The electron delocalization in π system is related to the resonance form. In according to this electron density distribution and HOMO/LUMO values of 1,3- bisdicyanovinylindane were simulated and calculated by Material Studio 4.3, absorption measurement and cyclic- voltammograms. The 1,3-bisdicyanovinylindane is one of the most attracted acceptor units in D-π-A system. This attempt is useful to determine more detailed characteristics of the energy potentials.
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| 키워드 |
Keywords: HOMO, LUMO, absorption, cyclicvoltammetry, 1,3-bisdicyanovinylindane, D-π-A
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| 학회지 |
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| Reference |
http://www.koreascience.or.kr/article/ArticleFullRecord.jsp?cn=OSGGBT_2013_v25n2_89 |
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