| 발행년도/권호 |
2012 년 / 권호: V.24,no.2,Jun |
| 논문제목1(원어) |
Photoinitiator-free Photo-reactive Coloration of Wool Fabrics Using C.I. Reactive Black 5 |
| 논문제목2(타언어) |
Photoinitiator-free Photo-reactive Coloration of Wool Fabrics Using C.I. Reactive Black 5 |
| 저자(원어) |
Yuanyuan Dong and Jinho Jang |
| 저자(타언어) |
Yuanyuan Dong and Jinho Jang |
| 소속(원어) |
Kumoh National Institute of Technology |
| 소속(타언어) |
Kumoh National Institute of Technology |
| 시작/끝
페이지 |
97 ~ 105 총페이지 : 9 |
| 언어(원어) |
English |
| 초록 |
Abstract: Compared with conventional adsorption-based coloration, the photoreactions of dyes such as photo-copolymerization
and photo-crosslinking under UV irradiation can be employed for the coloration of textiles, which can be carried out without
salt addition at room temperature. C.I. Reactive Black 5, a homo-bifunctional reactive dye containing two sulfatoethylsulfone
groups, is used as a photo-reactive dye for wool fibers. Upon UV irradiation, the photo-reactive dye was grafted onto wool
fabrics without photoinitiators. Since the disulfide bonds in the cystine residues of wool can be easily photodecomposed to
active thiyl radicals which initiate the polymerization, the dye can be polymerized to an oligomeric dye of a degree of
polymerization of 12 or more. The grafted fabrics reached a grafting yield of 2.3% o.w.f. and a color yield (K/S) of 18.2 by
the photografting of an aqueous dye concentration of 9% using a UV energy of 25J/cm2. Furthermore, the photochemically dyed
wool fabric showed higher colorfastness properties to light, laundering and rubbing comparable to conventional reactive dyeing. |
| 키워드 |
Keywords: wool, C.I. Reactive Black 5, UV irradiation, photografting, color yield |
| 학회지 |
|
| Reference |
http://www.koreascience.or.kr/article/ArticleFullRecord.jsp?cn=OSGGBT_2012_v24n2_97 |
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