| 발행년도/권호 |
2012 년 / 권호: V.24,no.1,Mar |
| 논문제목1(원어) |
PET 말단에 대한 인계난연제의 라디칼계 부가반응 (2)
-리소시놀비스다이페닐포스페이트의 반응- |
| 논문제목2(타언어) |
Radical Addition Reaction of Phosphorous based Flame Retardant
with End Groups of PET (2)
- Reaction of Resorcinol bis(diphenyl phosphate) - |
| 저자(원어) |
김민관 ․ 손광호1 ․ 김한도 |
| 저자(타언어) |
경북대학교 기능물질공학과, 1김천대학교 소방학과 |
| 소속(원어) |
Minkwan Kim, Kwang Ho Sohn1 and Han Do Ghim |
| 소속(타언어) |
Kyungpook National University |
| 시작/끝
페이지 |
39 ~ 44 총페이지 : 6 |
| 언어(원어) |
Korean |
| 초록 |
To improve flame retardation of poly(ethylene terephthalate) (PET) against burning, resorcinol bis(diphenyl
phosphate) (RDP), phosphorous containing flame retardant, was incorporated into PET backbone by radical reaction pathway.
Radical endcapping of PET with RDP was confirmed by spectroscopic and thermal analysis. From 400 MHz 31P solid state
FT-NMR spectrum of PET with RDP (PET-RDP), phosphorus spectra peak in RDP was found at ca. -10 ppm. Furthermore, P-C
bond stretching vibration peaks were found ca. 530 cm-1 in FT-IR spectrums of PET-RDP. These results indicated that RDP can
be chemically bound at the ends of PET by radical addition method. Thermal characteristics of pure PET (pPET) and PET-RDP
were measured and evaluated by TGA thermal analysis. There was not significant changes in thermal characteristics of
PET-RDP compared to that of pPET. |
| 키워드 |
poly(ethylene terephthalate), resorcinol bis(diphenyl phosphate), radical addition reaction, flame retardant,
31P solid state FT-NMR, TGA analysis |
| 학회지 |
|
| Reference |
http://www.koreascience.or.kr/article/ArticleFullRecord.jsp?cn=OSGGBT_2012_v24n1_39 |
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